| Issue |
SHS Web Conf.
Volume 49, 2018
International Cooperation for Education about Standardization 2018 (ICES 2018) Conference Joint International Conference with 5th ACISE (Annual Conference on Industrial and System Engineering) and World Standard Cooperation Academic Day
|
|
|---|---|---|
| Article Number | 02018 | |
| Number of page(s) | 7 | |
| Section | Engineering | |
| DOI | https://doi.org/10.1051/shsconf/20184902018 | |
| Published online | 02 October 2018 | |
Determination of copper metals in leachate using potentiometric method by concentration cells
Department of Chemistry, Faculty of Mathematic and Natural Sciences, Sriwijaya University
* Corresponding author: suheryanto_mhg254@yahoo.com
The potentiometric method of cell type concentration is used to analyze the copper metal in leachate. This method is relatively good because it has a correlation coefficient of 0.9997 and linear region in the concentration range 1×10-5 1×10-3 mol L-1. The precision of this potentiometric method is low because the persent of RSD produced is 0.6% with an average accuracy 0f 95.35%. The detection limit (LoD) of the measurable method is 1.085×10-6 mol L-1 with LoQ 1.313×10-6 mol L-1. While the LoD instrument 1.217×10-6 mol L-1 and LoQ 1.560×10-6 mol L-1. In addition, this method is very selective with the selectivity coefficient of -3.7 and it has uncertainty of measurement 9.7×10-7 ± 1.282×10-6 to 9.12×10-5 ± 3.5×10-5. Potentiometric method of cell type of concentration has an optimum condition at pH5 and temperature 30˚C.The conditions of copper in leachate water renged from 9.253×10-5 to 8.696×10-4 mol L-1
Key words: potentiometric / copper / leachate / concentration cell
© The Authors, published by EDP Sciences, 2018
This is an open access article distributed under the terms of the Creative Commons Attribution License 4.0 (http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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